(C(H)_(3))_(2)CHC(H)_(2)C(H)_(2)OH+HBr-|||-OCH3-|||-b. +H 过量)-|||-CH2CH 2OCH3-|||-C. +HT 过量)→-|||-0 CH3-|||-d. (C(H)_(3))_(2)CHBr+NaO(C)_(2)(H)_(5)-|||-e. (H)_(3)(C(H)_(2))3CHC(H)_(3)xrightarrow [高温](KMn{O)_(4)}-|||-OH-|||-O-|||-f.-|||-HIO4 CH3COH +CH3 CH2CHO-|||-0-|||-HIO4 CH3CCH 2CH2 CH2CHO-|||-g.-|||-OH-|||-h. +Br2→-|||-CH3-|||-i. CH3(CH 2)2 CHCH2CH3-浓H2SO4-|||-OH

equiv CC(H)_(2)C(H)_(2)OH 与 (H)_(3)C=!=!= C(C)_(2)OH-|||-CH2OH-|||-b. 与 CH3-|||-

(H)_(2)=CHC(H)_(2)OH-|||-OCH3-|||-CH3CH2CHCHCH3-|||-OH-|||-OH-|||-CH3CH2CHCHCH2

练习10.1 命名下列化合物或写出结构式:-|||-(1) _(2)(H)_(5)OCH=CHC(H)_(2)C(H)_(3)-|||-(2)CH3 OCH2C

(C(H)_(3)C(H)_(2))_(2)C=C(H)_(2)-|||-b. CH3CH2 CH2CCH 2(CH2)2 CH3-|||-C. (H)_(3)

(H)_(3)C(H)_(2)CH=C(H)_(2)xrightarrow ({H)_(2)S(O)_(4)}-|||-b. (C(H)_(3))_(2)C=C

完成下列反应式：(1)(H)_(3)C(H)_(2)C(H)_(2)Cequiv CH+HCl (过量)→(2)(H)_(3)C(H)_(2)C(H)_(2)C

(H)_(2)=CH-CH-C(H)_(3)-|||-C. (H)_(2)=CH-C(H)_(2) D. ((C{H)_(3))}_(2)-C(H)_(2)

下列自由基中最稳定的是( )。 (A)(CH3)2CHC H2CH2↑(B)(CH3)2C CHCHCH3 (C)(CH3)2CH2CH3-|||-(H)_(

8.写出下列反应的产物。-|||-(1) (H)_(3)C(H)_(2)C(H)_(2)C=CH+HBr (过量)→-|||-(2)CH3 CH2C=CCH2C

3.命名下列化合物。-|||-Br-|||-(1)C(H)_(3)CH(C(H)_(2)C(H)_(3))CHC(H)_(3)-|||-(2) CH3CH2CH