反应 (g)+2Y(g)=3Z(g) 在恒压和1000K时的 Delta (H)_(m) 为 cdot mo(L)^-1 Delta (S)_(m) 为-|||-] cdot mo(l)^-1cdot (K)^-1, 则下列关系中不正确的是 () 。-|||-(A) (Delta )_(r)(U)_(m)=(Delta )_(r)(H)_(m) (B) (Delta )_(r)(G)_(m)=0-|||-(C) (Delta )_(t)(U)_(m)=TDelta ({S)_(m)} (D) (Delta )_(r)(G)_(m)=(Delta )_(r)(H)_(m)

)(m)^2cdot mo(l)^-1-|||-_(m)(NaOH)=2.172times (10)^-2(S)_(cdot cdot )(m)^2cdot m

-285.8 -132.5 -230.0-|||-_(m)/(1cdot (K)^-1cdot mo(L)^-1) 111.3 69.9 113.4 -10.7

27.C6H6的正常熔点为5℃,摩尔熔化焓为 ] cdot mo(l)^-1,-|||-_(P(m))=126.8Jcdot (k)^-1cdot mo(l)^

667 6.667 6.664设测定值总体为^-11(m)^3cdot k(g)^-1 s^-2,^-11(m)^3cdot k(g)^-1 s^-2,

2、反应NH4HS(s )已 )+(H)_(2)S(g) 的 Delta (H)_(m)(298K)=93.72kJcdot mo(l)^-1, 设 Delta

(9)已知反应 _(2)(g)+3(H)_(2)(g)=2N(H)_(3)(g) 的 Delta (H)_(m)^theta (298.15k)=-92.22

(H)_(2)(g)+(O)_(2)(g)=!=!= 2(H)_(2)O(l) Delta (H)_(3)=-572kJcdot mo(l)^-1-|||-_

7.630K时反应 (s)leftharpoons 2Hg(g)+(O)_(2)(g) 的 (Delta )_(T)(G)_(m)=44.3kJcdot mo(

(log )_(k)^-1-|||-(H)_(3)(g)+5(O)_(2)(g)=4NO(g)+6(H)_(2)O(g)-|||-Delta (H)_(3)=-

_(2)(g)+dfrac (1)(2)(O)_(2)(g)=!=!= (H)_(2)O(1) Delta (H)_(2)=-285.5kJ-|||-cdot